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Biogeosciences An interactive open-access journal of the European Geosciences Union
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Volume 13, issue 2
Biogeosciences, 13, 567-582, 2016
https://doi.org/10.5194/bg-13-567-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Biogeosciences, 13, 567-582, 2016
https://doi.org/10.5194/bg-13-567-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 02 Feb 2016

Research article | 02 Feb 2016

The nature of organic carbon in density-fractionated sediments in the Sacramento-San Joaquin River Delta (California)

S. G. Wakeham1 and E. A. Canuel2 S. G. Wakeham and E. A. Canuel
  • 1Skidaway Institute of Oceanography, The University of Georgia, 10 Ocean Science Circle, Savannah, GA 31411, USA
  • 2Virginia Institute of Marine Science, College of William and Mary, P.O. Box 1346, Gloucester Point, VA 23062, USA

Abstract. Rivers are the primary means by which sediments and carbon are transported from the terrestrial biosphere to the oceans but gaps remain in our understanding of carbon associations from source to sink. Bed sediments from the Sacramento-San Joaquin River Delta (CA) were fractionated according to density and analyzed for sediment mass distribution, elemental (C and N) composition, mineral surface area, and stable carbon and radiocarbon isotope compositions of organic carbon (OC) and fatty acids to evaluate the nature of organic carbon in river sediments. OC was unevenly distributed among density fractions. Mass and OC were in general concentrated in mesodensity (1.6–2.0 and 2.0–2.5gcm−3) fractions, comprising 84.0±1.3% of total sediment mass and 80.8±13.3% of total OC (TOC). Low-density (<1.6gcm−3) material, although rich in OC (34.0±2.0% OC) due to woody debris, constituted only 17.3±12.8% of TOC. High-density (>2.5gcm−3) organic-poor, mineral-rich material made-up 13.7±1.4% of sediment mass and 2.0±0.9% of TOC. Stable carbon isotope compositions of sedimentary OC were relatively uniform across bulk and density fractions (δ13C −27.4±0.5‰). Radiocarbon content varied from Δ14C values of −382 (radiocarbon age 3800yr BP) to +94‰ (modern) indicating a mix of young and old OC. Fatty acids were used to further constrain the origins of sedimentary OC. Short-chain n-C14n-C18 fatty acids of algal origin were depleted in 13C (δ13C −37.5 to −35.2‰) but were enriched in 14C (Δ14C>0) compared to long-chain n-C24n-C28 acids of vascular plant origins with higher δ13C (−33.0 to −31.0‰) but variable Δ14C values (−180 and 61‰). These data demonstrate the potentially complex source and age distributions found within river sediments and provide insights about sediment and organic matter supply to the Delta.

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Bed sediments from the Sacramento-San Joaquin River Delta (CA) were fractionated according to density and analyzed for sediment mass distribution, elemental (C and N) composition, mineral surface area, and stable carbon and radiocarbon isotope compositions of organic carbon (OC) and fatty acids to evaluate the nature of organic carbon in river sediments. These data demonstrate the complex source and age distributions within river sediments.
Bed sediments from the Sacramento-San Joaquin River Delta (CA) were fractionated according to...
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