Journal cover Journal topic
Biogeosciences An interactive open-access journal of the European Geosciences Union
Journal topic
Volume 12, issue 4
Biogeosciences, 12, 921–932, 2015
https://doi.org/10.5194/bg-12-921-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
Biogeosciences, 12, 921–932, 2015
https://doi.org/10.5194/bg-12-921-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 16 Feb 2015

Research article | 16 Feb 2015

Long-term spatial and temporal variation of CO2 partial pressure in the Yellow River, China

L. Ran1, X. X. Lu1,2, J. E. Richey3, H. Sun4, J. Han4, R. Yu2, S. Liao5, and Q. Yi6 L. Ran et al.
  • 1Department of Geography, National University of Singapore, 117570, Singapore
  • 2College of Environment & Resources, Inner Mongolia University, Hohhot, 010021, China
  • 3School of Oceanography, University of Washington, Box 355351, Seattle, WA 98195-5351, USA
  • 4Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing, 100029, China
  • 5Tongguan Hydrographic Station, Yellow River Conservancy Commission, Tongguan, 714399, China
  • 6Toudaoguai Hydrographic Station, Yellow River Conservancy Commission, Baotou, 014014, China

Abstract. Carbon transport in river systems is an important component of the global carbon cycle. Most rivers of the world act as atmospheric CO2 sources due to high riverine CO2 partial pressure (pCO2). By determining the pCO2 from alkalinity and pH, we investigated its spatial and temporal variation in the Yellow River watershed using historical water chemistry records (1950s–1984) and recent sampling along the mainstem (2011–2012). Except the headwater region where the pCO2 was lower than the atmospheric equilibrium (i.e. 380 μatm), river waters in the remaining watershed were supersaturated with CO2. The average pCO2 for the watershed was estimated at 2810 ± 1985 μatm, which is 7-fold the atmospheric equilibrium. As a result of severe soil erosion and dry climate, waters from the Loess Plateau in the middle reaches had higher pCO2 than that from the upper and lower reaches. From a seasonal perspective, the pCO2 varied from about 200 μatm to > 30 000 μatm with higher pCO2 usually occurring in the dry season and lower pCO2 in the wet season (at 73% of the sampling sites), suggesting the dilution effect of water. While the pCO2 responded exponentially to total suspended solids (TSS) export when the TSS concentration was less than 100 kg m−3, it decreased slightly and remained stable if the TSS concentration exceeded 100 kg m−3. This stable pCO2 is largely due to gully erosion that mobilizes subsoils characterized by low organic carbon for decomposition. In addition, human activities have changed the pCO2 dynamics. Particularly, flow regulation by dams can diversely affect the temporal changes of pCO2, depending on the physiochemical properties of the regulated waters and adopted operation scheme. Given the high pCO2 in the Yellow River waters, large potential for CO2 evasion is expected and warrants further investigation.

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This paper investigated the spatial and temporal variations of pCO2 in the Yellow River watershed. While the pCO2 responded exponentially to total suspended solids (TSS) export when the TSS concentration was less than 100 kg m-3, it decreased and remained stable thereafter if the TSS concentration was greater than 100 kg m-3. The average pCO2 for the watershed was estimated at 2810±1985 μatm, indicating a large potential for CO2 evasion.
This paper investigated the spatial and temporal variations of pCO2 in the Yellow River...
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