Journal cover Journal topic
Biogeosciences An interactive open-access journal of the European Geosciences Union
Biogeosciences, 11, 4599-4613, 2014
https://doi.org/10.5194/bg-11-4599-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
Research article
01 Sep 2014
Interannual sea–air CO2 flux variability from an observation-driven ocean mixed-layer scheme
C. Rödenbeck1, D. C. E. Bakker2, N. Metzl3, A. Olsen4,5, C. Sabine6, N. Cassar7, F. Reum1, R. F. Keeling8, and M. Heimann1 1Max Planck Institute for Biogeochemistry, Jena, Germany
2School of Environmental Sciences, University of East Anglia, Norwich Research Park, Norwich, UK
3LOCEAN-IPSL, CNRS, Paris, France
4Geophysical Institute, University of Bergen and Bjerknes Centre for Climate Research, Bergen, Norway
5Uni Climate, Uni Research AS and Bjerknes Centre for Climate Research, Bergen, Norway
6NOAA Pacific Marine Environmental Laboratory, Seattle, USA
7Division of Earth and Ocean Sciences, Duke University, Durham, USA
8Scripps Institution of Oceanography, University of California, San Diego, USA
Abstract. Interannual anomalies in the sea–air carbon dioxide (CO2) exchange have been estimated from surface-ocean CO2 partial pressure measurements. Available data are sufficient to constrain these anomalies in large parts of the tropical and North Pacific and in the North Atlantic, in some areas covering the period from the mid 1980s to 2011. Global interannual variability is estimated as about 0.31 Pg C yr−1 (temporal standard deviation 1993–2008). The tropical Pacific accounts for a large fraction of this global variability, closely tied to El Niño–Southern Oscillation (ENSO). Anomalies occur more than 6 months later in the east than in the west. The estimated amplitude and ENSO response are roughly consistent with independent information from atmospheric oxygen data. This both supports the variability estimated from surface-ocean carbon data and demonstrates the potential of the atmospheric oxygen signal to constrain ocean biogeochemical processes. The ocean variability estimated from surface-ocean carbon data can be used to improve land CO2 flux estimates from atmospheric inversions.

Citation: Rödenbeck, C., Bakker, D. C. E., Metzl, N., Olsen, A., Sabine, C., Cassar, N., Reum, F., Keeling, R. F., and Heimann, M.: Interannual sea–air CO2 flux variability from an observation-driven ocean mixed-layer scheme, Biogeosciences, 11, 4599-4613, https://doi.org/10.5194/bg-11-4599-2014, 2014.
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