1ETH Zurich, Institute of Geochemistry and Petrology, Zurich, Switzerland
2Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration, Seattle, Washington, USA
*now at: Atmospheric and Oceanic Sciences Program, Princeton University, Princeton, New Jersey, USA
**now at: Laboratoire de Géologie de Lyon, ENS Lyon, CNRS and UCBL, Lyon, France
Received: 23 Apr 2012 – Published in Biogeosciences Discuss.: 05 Jun 2012
Abstract. The cycling and transport of dissolved silicon (Si) in the ocean may be traced by its stable isotope composition, δ30Si. We present a dataset of δ30Si values along 103° W in the eastern South Pacific Ocean, ranging from the Antarctic Zone of the Southern Ocean (62° S) to the equatorial Pacific (12° S). At high southern latitudes, the uptake and associated isotope fractionation of Si by diatoms results in highly elevated δ30Si values (up to +3.2‰) in the summer mixed layer. High δ30Si values (+2‰) are also preserved in the high-latitude fossil winter mixed layer, documenting the efficient export of diatom opal beyond the maximum depth of winter convection. This elevated winter mixed layer δ30Si signature is introduced into the ocean interior by the subduction of Subantarctic Mode Water (SAMW) and Antarctic Intermediate Water (AAIW), whose northward spreading results in a strong isopycnal control on lower-thermocline and intermediate δ30Si values in the well-ventilated eastern South Pacific. Values of δ30Si are strongly conserved along SAMW and AAIW density levels as far north as 26° S, documenting the importance of the export of preformed Si from the surface Southern Ocean to lower latitudes. In contrast, in the equatorial Pacific, depressed δ30Si values in the mesopelagic ocean are observed, most likely documenting the combined influence of a North Pacific Si source as well as the accumulation of remineralized Si within the eastern equatorial Pacific shadow zone. At depth, δ30Si values in the South Pacific remain indistinguishable from deep Southern Ocean values of +1.25‰, even within Si-rich and oxygen-poor deep waters returning from the North Pacific. This homogeneity implies that the dissolution of opal plays a negligible role in altering the δ30Si value of deep waters as they traverse the deep Pacific Ocean.
Revised: 17 Sep 2012 – Accepted: 05 Oct 2012 – Published: 01 Nov 2012
de Souza, G. F., Reynolds, B. C., Johnson, G. C., Bullister, J. L., and Bourdon, B.: Silicon stable isotope distribution traces Southern Ocean export of Si to the eastern South Pacific thermocline, Biogeosciences, 9, 4199-4213, doi:10.5194/bg-9-4199-2012, 2012.