Biogeosciences www.biogeosciences.net 1726-4170 1726-4189 7 2 2010 10.5194/bg-7-753-2010 http://www.biogeosciences.net/7/753/2010/ http://www.biogeosciences.net/7/753/2010/bg-7-753-2010.html http://www.biogeosciences.net/7/753/2010/bg-7-753-2010.pdf 753 762 2010-02-25 Exchange of carbonyl sulfide (COS) between the atmosphere and various soils in China J. Liu C. Geng Y. Mu yjmu@rcees.ac.cn Y. Zhang Z. Xu H. Wu State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China Chinese Research Academy of Environmental Sciences, Beijing, China National Institute of Metrology, Beijing, China Using a dynamic enclosure, the exchange rates of carbonyl sulfide (COS) between the atmosphere and 18 soils from 12 provinces in China were investigated. The emission or uptake of COS from the soils was highly dependent on the soil type, soil temperature, soil moisture, and atmospheric COS mixing ratio. In general, with the only exception being paddy soils, the soils in this investigation acted as sinks for atmospheric COS under wide ranges of soil temperature and soil moisture. Two intensively investigated wheat soils and one forest soil had optimal soil temperatures for COS uptake of around 15 °C, and the optimal soil water content varied from 13% to 58%. COS emission rates from the two paddy soils increased exponentially with increment of the soil temperature, and decreased with increasing the soil water content. However, negligible emission was found when the paddy soils were under waterlogging status. The observed compensation points for various soils were different and increased significantly with soil temperature. The laboratory simulation agreed with the preliminary field measurements for the paddy soil in Jiaxing, Zhejiang province. % vor jede Referenz Adams, D. F., Farwell, S. O., Robinson, E., Pack, M. R., and Bamesberger, W. L.: Biogenic sulfur source strengths, Environ. 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