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	<journal>
		<journal_title>Biogeosciences</journal_title>
		<journal_url>www.biogeosciences.net</journal_url>
		<issn>1726-4170</issn>
		<eissn>1726-4189</eissn>
		<volume_number>5</volume_number>
		<issue_number>2</issue_number>
		<publication_year>2008</publication_year>
	</journal>
	<doi>10.5194/bg-5-535-2008</doi>
	<article_url>http://www.biogeosciences.net/5/535/2008/</article_url>
	<abstract_html>http://www.biogeosciences.net/5/535/2008/bg-5-535-2008.html</abstract_html>
	<fulltext_pdf>http://www.biogeosciences.net/5/535/2008/bg-5-535-2008.pdf</fulltext_pdf>
	<start_page>535</start_page>
	<end_page>547</end_page>
	<publication_date>2008-04-10</publication_date>
	<article_title content_type="html">Sea-surface CO&lt;sub&gt;2&lt;/sub&gt; fugacity in the subpolar North Atlantic</article_title>
	<authors>
		<author numeration="1" affiliations="1,2,3">
			<name>A. Olsen</name>
			<email>are.olsen@gfi.uib.no</email>
		</author>
		<author numeration="2" affiliations="1">
			<name>K. R. Brown</name>
		</author>
		<author numeration="3" affiliations="3">
			<name>M. Chierici</name>
		</author>
		<author numeration="4" affiliations="1,2">
			<name>T. Johannessen</name>
		</author>
		<author numeration="5" affiliations="1">
			<name>C. Neill</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Bjerknes Centre for Climate Research, University of Bergen, Bergen, Norway</affiliation>
		<affiliation numeration="2" content_type="html">Geophysical Institute, University of Bergen, Bergen, Norway</affiliation>
		<affiliation numeration="3" content_type="html">Marine Chemistry, Department of Chemistry, Göteborg University, Göteborg, Sweden</affiliation>
	</affiliations>
	<abstract content_type="html">We present the first year-long subpolar trans-Atlantic set of surface
seawater CO&lt;sub&gt;2&lt;/sub&gt; fugacity (&lt;i&gt;f&lt;/i&gt;CO&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;sw&lt;/sup&gt;) data. The data were
obtained aboard the MV &lt;i&gt;Nuka Arctica&lt;/i&gt; in 2005 and provide a quasi-continuous picture of the
&lt;i&gt;f&lt;/i&gt;CO&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;sw&lt;/sup&gt; variability between Denmark and Greenland.
Complementary real-time high-resolution data of surface chlorophyll-&lt;i&gt;a&lt;/i&gt; (chl-&lt;i&gt;a&lt;/i&gt;)
concentrations and mixed layer depth (MLD) estimates have been collocated
with the &lt;i&gt;f&lt;/i&gt;CO&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;sw&lt;/sup&gt; data.
Off-shelf &lt;i&gt;f&lt;/i&gt;CO&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;sw&lt;/sup&gt; data exhibit a pronounced seasonal
cycle. In winter, surface waters are saturated to slightly supersaturated
over a wide range of temperatures. Through spring and summer,
 &lt;i&gt;f&lt;/i&gt;CO&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;sw&lt;/sup&gt; decreases by approximately 60 &amp;mu;atm,
due to biological carbon consumption, which is not fully counteracted by the
&lt;i&gt;f&lt;/i&gt;CO&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;sw&lt;/sup&gt; increase due to summer warming. The changes are
synchronous with changes in chl-&lt;i&gt;a&lt;/i&gt; concentrations and MLD, both of which are
exponentially correlated with &lt;i&gt;f&lt;/i&gt;CO&lt;sub&gt;2&lt;/sub&gt;&lt;sup&gt;sw&lt;/sup&gt; in off-shelf
regions.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Bellerby, R. G. J., Olsen, A., Furevik, T., and Anderson, L. G.: Response of the surface ocean CO&lt;sub&gt;2&lt;/sub&gt; system in the Nordic Seas and northern North Atlantic to climate change, in The Nordic Seas: An Integrated Perspective, edited by: Drange, H., Dokken, T., Furevik, T., Gerdes, R., and Berger, W., Geophys. Monogr. Ser., 158, 189&amp;ndash;197, AGU, Washington D.C., 2005. </reference>
		<reference numeration="2" content_type="text"> Boutin, J., Etcheto, J., Dandonneau, Y., Bakker, D. C. E., Feely, R. A., Inoue, H. Y., Ishii, M., Ling, R. D., Nightingale, P. D., Metzl, N., and Wanninkhof, R.: Satellite sea surface temperature: A powerful tool for interpreting in situ pCO&lt;sub&gt;2&lt;/sub&gt; in the equatorial Pacific Ocean, Tellus B, 51, 490&amp;ndash;508, 1999. </reference>
		<reference numeration="3" content_type="text"> Chierici, M., Fransson, A., and Nojiri, Y.: Biogeochemical processes as drivers of surface fCO&lt;sub&gt;2&lt;/sub&gt; in contrasting provinces in the North Pacific Ocean, Global Biogeochem. Cy., 20, GB1009, doi:10.1029/2004GB002356, 2006. </reference>
		<reference numeration="4" content_type="text"> Cooper, D. J., Watson, A. J., and Ling, R. D.: Variation of pCO&lt;sub&gt;2&lt;/sub&gt; along a North Atlantic shipping route (U.K. to the Caribbean): A year of automated observations, Mar. Chem., 72, 151&amp;ndash;169, 1998. </reference>
		<reference numeration="5" content_type="text"> Corbiere, A., Metzl, N., Reverdin, G., Brunet, C., and Takahashi, T.: Interannual and decadal variability of the oceanic carbon sink in the North Atlantic subpolar gyre, Tellus B, 59, 168&amp;ndash;178, 2007. </reference>
		<reference numeration="6" content_type="text"> Cosca, C. E., Feely, R. A., Boutin, J., Etcheto, J., McPhaden, M. J., Chavez, F. P., and Strutton, P. G.: Seasonal and interannual CO&lt;sub&gt;2&lt;/sub&gt; fluxes for the central and eastern equatorial Pacific Ocean as determined from fCO&lt;sub&gt;2&lt;/sub&gt;-SST relationships, J. Geophys. Res., 108, 3278, doi:10.1029/2000JC000677, 2003. </reference>
		<reference numeration="7" content_type="text"> Feely, R. A., Wanninkhof, R., Milburn, H. B., Cosca, C. E., Stapp, M., and Murphy, P. P.: A new automated underway system for making high precision pCO&lt;sub&gt;2&lt;/sub&gt; measurements onboard research ships, Anal. Chim. Acta, 377, 185&amp;ndash;191, 1998. </reference>
		<reference numeration="8" content_type="text"> Frantantoni, D. M.: North Atlantic surface circulation during the 1990&apos;s observed with satellite-tracked drifters, J. Geophys. Res., 106, 22 067&amp;ndash;22 093, 2001. </reference>
		<reference numeration="9" content_type="text"> Gruber, N., Sarmiento, J. L., and Stocker, T. F.: An improved method for detecting anthropogenic CO&lt;sub&gt;2&lt;/sub&gt; in the oceans, Global Biogeochem. Cy., 10, 809&amp;ndash;837, 1996. </reference>
		<reference numeration="10" content_type="text"> Hansen, B. and Østerhus, S.: North Atlantic-Nordic Seas exchanges, Prog. Oceanogr., 45, 109&amp;ndash;208, 2000. </reference>
		<reference numeration="11" content_type="text"> Holliday, N. P., Waniek, J. J., Davidson, R., Wilson, D., Brown, L., Sanders, R., Pollard, R. T., and Allen, J. T.: Large-scale physical controls on phytoplankton growth in the Irminger Sea Part I: Hydrographic zones, mixing and stratification, J. Mar. Syst., 59, 201&amp;ndash;218, 2006. </reference>
		<reference numeration="12" content_type="text"> Kalnay, E., Kanamitsu, M., Kistler, R., Collins, W., Deaven, D., Gandin, L., Iredell, M., Saha, S., White, G., Woollen, J., Zhu, Y., Chelliah, M., Ebisuzaki, W., Higgins, W., Janowiak, J., Mo, K. C., Ropelewski, C., Leetmaa, A., Reynolds, R., and Jenne, R.: The NCEP/NCAR Reanalysis Project, B. Am. Meteorol. Soc., 77, 437&amp;ndash;471, 1996. </reference>
		<reference numeration="13" content_type="text"> Lacan, F. and Jeandel, C.: Subpolar Mode Water formation traced by neodynium isotopic composition, Geophys. Res. Lett., 31, L14306, doi:10.1029/2004GL019747, 2004. </reference>
		<reference numeration="14" content_type="text"> Lee, A. J.: North Sea: Physical Oceanography, in: The North-West European shelf seas: the seabed and the sea in motion, part II physical and chemical oceanography and chemical resources, edited by: Banner, F. T., Collins, M. B., and Massie, K. S., Elsevier Oceanography Series, 24b, 467&amp;ndash;493, 1980. </reference>
		<reference numeration="15" content_type="text"> Lee, K., Tong, L. T., Millero, F. J., Sabine, C. L., Dickson, A. G., Goyet, C., Park, G.-H., Wanninkhof, R., Feely, R. A., and Key, R. M.: Global relationships of total alkalinity with salinity and temperature in surface waters of the world&apos;s oceans, Geophys. Res. Lett., 33, L19605, doi:10.1029/2006GL027207, 2006. </reference>
		<reference numeration="16" content_type="text"> Lèvy, M., Lehan, Y., Andrè, J.-M., Mèmery, L., Loisel, H., and Heifetz, E.: Production regimes in the northeast Atlantic: A study based on Sea-viewing Wide Field of view Sensor (SeaWiFS) chlorophyll and ocean general circulation model mixed layer depth, J. Geophys. Res., 110, C07S10, doi:10.1029/2004JC002771, 2005. </reference>
		<reference numeration="17" content_type="text"> Lueker, T. J., Dickson, A. G., and Keeling, C. D.: Ocean pCO&lt;sub&gt;2&lt;/sub&gt; calculated from dissolved inorganic carbon, alkalinity and equations for K$_1$ and K&lt;sub&gt;2&lt;/sub&gt;: validation based on laboratory measurements of CO&lt;sub&gt;2&lt;/sub&gt; in gas and seawater at equilibrium, Mar. Chem., 70, 105&amp;ndash;119, 2000. </reference>
		<reference numeration="18" content_type="text"> Lüger, H., Wallace, D. W. R., Körtzinger, A., and Nojiri, Y.: The pCO&lt;sub&gt;2&lt;/sub&gt; variability in the midlatitude North Atlantic Ocean during a full annual cycle, Global Biogeochem. Cy., 18, GB3023, doi:10.1029/2003GB002200, 2004. </reference>
		<reference numeration="19" content_type="text"> McCartney, M. S. and Talley, L. D.: The Subpolar Mode Waters of the North Atlantic Ocean, J. Phys. Oceanogr., 12, 1169&amp;ndash;1188, 1982. </reference>
		<reference numeration="20" content_type="text"> McClain, C. R., Feldmann, G. C., and Hooker, S. B.: An overview of the SeaWiFS project and strategies for producing climate research quality global ocean bio-optical time series, Deep-Sea Res. II, 51, 5&amp;ndash;42, 2004. </reference>
		<reference numeration="21" content_type="text"> McCulloch, M. E., Alves, J. O. S., and Bell, M. J.: Modelling shallow mixed layers in the northeast Atlantic, J. Mar. Syst., 52, 107&amp;ndash;119, 2004. </reference>
		<reference numeration="22" content_type="text"> Mehrbach, C., Culberson, C. H., Hawley, J. E., and Pytkowicz, R. M.: Measurement of apparent dissociation contants of carbonic acid in seawater at atmospheric pressure, Limnol. Oceanogr., 18, 533&amp;ndash;541, 1973. </reference>
		<reference numeration="23" content_type="text"> Nakaoa, S. I., Aoki, A., Nakazawa, T., Hashida, G., Morimoto, S., Yamanouchi, T., and Yoshikawa-Inoue, H.: Temporal and spatial variations of the oceanic pCO&lt;sub&gt;2&lt;/sub&gt; and air- sea CO&lt;sub&gt;2&lt;/sub&gt; flux in the Greenland Sea and Barents Sea, Tellus B, 58, 148&amp;ndash;161, 2006. </reference>
		<reference numeration="24" content_type="text"> Nelson, N. B., Bates, N. R., Siegel, D. A., and Michaels, A. F.: Spatial variability of the CO&lt;sub&gt;2&lt;/sub&gt; sink in the Sargasso Sea, Deep-Sea Res. II, 48, 1801&amp;ndash;1821, 2001. </reference>
		<reference numeration="25" content_type="text"> Nightingale, P. D., Malin, G., Law, C. S., Watson, A. J., Liss, P. D., Liddicoat, M. I., Boutin, J., and Upstill-Goddard, R. C.: In situ evaluation of air-sea gas exchange parameterizations using novel conservative and volatile tracers, Global Biogeochem. Cy., 14, 373&amp;ndash;387, 2000 </reference>
		<reference numeration="26" content_type="text"> Olsen, A., Wanninkhof, R., Triñanes, J., and Johannessen, T.: The effect of wind speed products and wind speed-gas exchange relationships on interannual variability of the air-sea CO&lt;sub&gt;2&lt;/sub&gt; gas transfer velocity, Tellus B, 57, 95&amp;ndash;106, 2005. </reference>
		<reference numeration="27" content_type="text"> Olsen, A., Triñanes, J. A., and Wanninkhof, R.: Sea-air flux of CO&lt;sub&gt;2&lt;/sub&gt; in the Caribbean Sea estimated using in situ and remote sensing data, Remote Sens. Environ., 89, 309&amp;ndash;325, 2004. </reference>
		<reference numeration="28" content_type="text"> Olsen, A., Bellerby, R. G. J., Johannessen, T., Omar, A. M., and Skjelvan, I.: Interannual variability in the wintertime air-sea flux of carbon dioxide in the northern North Atlantic, 1981&amp;ndash;2003, Deep-Sea Res. I, 50, 1323&amp;ndash;1338, 2003. </reference>
		<reference numeration="29" content_type="text"> Orvik, K. A. and Niiler, P.: Major pathways of Atlantic water in the northern North Atlantic and Nordic Seas toward Arctic, Geophys. Res. Lett., 29(19), 1896, doi:10.1029/2002GL015002, 2002. </reference>
		<reference numeration="30" content_type="text"> Park, G. H., Lee, K., Wanninkhof, R., Feely, R. A.: Empirical temperature-based estimates of variability in the oceanic uptake of CO&lt;sub&gt;2&lt;/sub&gt; over the past two decades, J. Geophys. Res, 111(C7), C07S07, doi:10.1029/2005JC003090, 2006. </reference>
		<reference numeration="31" content_type="text"> Pèrez, F. F., Àlvarez, M., and Rios, A. F.: Improvements on the back-calculation technique for estimating anthropogenic CO&lt;sub&gt;2&lt;/sub&gt;, Deep-Sea Res. I, 49, 859&amp;ndash;875, 2002. </reference>
		<reference numeration="32" content_type="text"> Pollard, R. T., Read, J. F., Holiday, N. P., and Leach, H.: Water Masses and circulation pathways through the Iceland Basin during Vivaldi 1996, J. Geophys. Res., 109, C04004, doi:10.1029/2003JC002067, 2004. </reference>
		<reference numeration="33" content_type="text"> Prentice, I. C., Farquhar, G. D., Fasham, M. J. R., Goulden, M. L., Heimann, M., Jaramillo, J., Kheshgi, H. S., Le Quèrè, C., Scholes, R., and Wallace, D. W. R.: The Carbon Cycle and Atmospheric Carbon Dioxide, in Climate Change 2001: The Scientific Basis, Contribution of Working Group I to the Third Assessment Report of the intergovernmental Panel on Climate Change, edited by: Houghton, J. T., Ding, Y., Griggs, D. J., Noguer, M., van der Linden, P. J., Dai, X., Maskell, K., and Johnson, C. A., Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 881 pp., 2001. </reference>
		<reference numeration="34" content_type="text"> Raynaud, S., Orr, J. C., Aumont, O., Rodgers, K. B., and Yiou, P.: Interannual-to-decadal variability of North Atlantic air-sea CO&lt;sub&gt;2&lt;/sub&gt; fluxes, Ocean Sci., 2, 43&amp;ndash;60, 2006. </reference>
		<reference numeration="35" content_type="text"> Reverdin, G., Niiler, P. P., and Valdimirsson, H.: North Atlantic Surface Currents, J. Geophys. Res., 108(C1), 3002, doi:10.1029/2001JC001020, 2003. </reference>
		<reference numeration="36" content_type="text"> Roy, R. N., Roy, L. N., Vogel, K. M., Moore, C. P., Pearson, T., Good, C. E., Millero, F. J., and Campbell, D. M.: Determination of the ionization constants of carbonic acid in seawater, Mar. Chem., 44, 249&amp;ndash;268, 1993. </reference>
		<reference numeration="37" content_type="text"> Smith, S. R., Legler, D. M., and Verzone, K. V.: Quantifying uncertainties in NCEP reanalyses using high-quality research vessel observations, J. Climate, 14, 4062&amp;ndash;4072, 2001. </reference>
		<reference numeration="38" content_type="text"> Stephens, M. P., Samuels, G., Olson, D. B., Fine, R. A., and Takahashi, T.: Sea-air flux of CO&lt;sub&gt;2&lt;/sub&gt; in the North Pacific using shipboard and satellite data, J. Geophys. Res., 100, 13 571&amp;ndash;13 583, 1995. </reference>
		<reference numeration="39" content_type="text"> Sverdrup, H. U.: On conditions for the vernal blooming of phytoplankton, J. Conc. Int. P. Exp. de la Mer, 18, 287&amp;ndash;295, 1953. </reference>
		<reference numeration="40" content_type="text"> Sweeney, C., Takahashi, T., and Gnanadesikan, A.: Spatial and temporal variability of surface water pCO&lt;sub&gt;2&lt;/sub&gt; and sampling strategies, in: A large-scale CO&lt;sub&gt;2&lt;/sub&gt; observing plan: In situ oceans and atmosphere, edited by: Bender, M., Doney, S., Feely, R. A., et al., National Technical Information Service, Springfield, Virginia, USA, 155&amp;ndash;175, 2002. </reference>
		<reference numeration="41" content_type="text"> Takahashi, T., Sutherland, S. C., Sweeney, C., Poisson, A., Metzel, N., Tilbrook, B., Bates, N., Wanninkhof, R., Feely, R. A., Sabine, C., Olafsson, J., and Nojiri,Y.: Global sea- air CO&lt;sub&gt;2&lt;/sub&gt; flux based on climatological ocean pCO&lt;sub&gt;2&lt;/sub&gt; and seasonal biological and temperature effects, Deep-Sea Res. II, 49, 1601&amp;ndash;1622, 2002. </reference>
		<reference numeration="42" content_type="text"> Takahashi, T., Olafsson, J., Goddard, J. G., Chipman, D. W., and Sutherland, S. C.: Seasonal variation of CO&lt;sub&gt;2&lt;/sub&gt; and nutrients in the high-latitude surface oceans: a comparative study, Global Biogeochem. Cy., 7, 843&amp;ndash;878, 1993. </reference>
		<reference numeration="43" content_type="text"> Taylor, A. H., Watson, A. J., Ainsworth, M., Robertson, J. E., and Turner, D. R.: A modelling investigation of the role of phytoplankton in the balance of carbon at the surface, Global Biogeochem. Cy., 5, 151&amp;ndash;171, 1991. </reference>
		<reference numeration="44" content_type="text"> Wallace, D. W. R.: Storage and transport of excess CO&lt;sub&gt;2&lt;/sub&gt; in the oceans: The JGOFS/WOCE global CO&lt;sub&gt;2&lt;/sub&gt; survey, in: Ocean Circulation and Climate: Observing and Modelling the Global Ocean, edited by: Siedler, G., Church, J., and Gould, J., Elsevier, New York, 489&amp;ndash;521, 2001. </reference>
		<reference numeration="45" content_type="text"> Wanninkhof, R., Olsen, A., and Triñanes, J.: Air-sea CO&lt;sub&gt;2&lt;/sub&gt; fluxes in the Caribbean Sea from 2002&amp;ndash;2004, J. Mar. Syst., 66, 272&amp;ndash;284, 2007. </reference>
		<reference numeration="46" content_type="text"> Wanninkhof, R., Lewis, E., Feely, R. A., and Millero, F. J.: The optimal carbonate dissociation constants for determining surface water pCO&lt;sub&gt;2&lt;/sub&gt; from alkalinity and total inorganic carbon, Mar. Chem., 65, 291&amp;ndash;301, 1999. </reference>
		<reference numeration="47" content_type="text"> Wanninkhof, R. and McGillis, W. R.: A cubic relationship between air-sea CO&lt;sub&gt;2&lt;/sub&gt; exchange and wind speed, Geophys. Res. Lett., 26(13), 1889&amp;ndash;1892, 1999. </reference>
		<reference numeration="48" content_type="text"> Wanninkhof, R. and Thoning, K.: Measurement of fugacity of CO&lt;sub&gt;2&lt;/sub&gt; in surface water using continuous and discrete sampling methods, Mar. Chem., 44, 189&amp;ndash;201, 1993. </reference>
		<reference numeration="49" content_type="text"> Wanninkhof, R.: Relationship Between Wind Speed and Gas Exchange Over the Ocean, J. Geophys. Res., 97, 7373&amp;ndash;7382, 1992. </reference>
		<reference numeration="50" content_type="text"> Watson, A. J., Robinson, C., Robertson, J. E., Williams, P. J. le B., and Fasham, M. J. R.: Spatial variability in the sink for atmospheric carbon dioxide in the North Atlantic, Nature, 350, 50&amp;ndash;53, 1991. </reference>
		<reference numeration="51" content_type="text"> Weiss, R. F.: Carbon dioxide in water and seawater: The solubility of a nonideal gas, Mar. Chem., 2, 201&amp;ndash;215, 1974. </reference>
		<reference numeration="52" content_type="text"> Weiss, R. and Price, B. A.: Nitrous oxide solubility in water and seawater, Mar. Chem., 8, 347&amp;ndash;359, 1980. </reference>
		<reference numeration="53" content_type="text"> Zeebe, R. and Wolf-Gladrov, D.: CO&lt;sub&gt;2&lt;/sub&gt; in seawater: equilibrium, kinetics, isotopes, Elsevier Oceanography Series 65, Elsevier, Amsterdam, 346 pp., 2001. </reference>
	</references>
</article>

